So I guess my question is, will there be an alternative tier 3, or another way to satisfy the pre-req.
No. All of the tier 3 skills are weapon specific. This was done intentionally to encourage people to use the corresponding weapon styles for the trees - 2HE for power, sword and board for defense, and master florentine for finesse. So yes, if you're dead-set on using master florentine, you can still get Slay, but you're gonna have to pick up a 2HE (or brawlers) if you want to use Devastating Strike.
Yes, you can re-spend the build you have invested in Master Warrior without re-learning everything.
Sean